This technology is a near infrared light-controlled method of olefin metathesis for polymer printing.
Light offers various benefits as an approach to pattern polymers for printing, as it is minimally invasive and harbors high temporal and spatial resolution. Despite this, current methods of photo-controlled polymer printing use high energy wavelengths of light and suffer from poor barrier penetration depth. As such, there is a need for low energy alternatives to enable efficient control over reactivity through physical barriers.
This method provides low energy light-controlled olefin metathesis with high levels of spatial and temporal resolution. Latent ruthenium olefin metathesis catalysts are activated using near infrared light in combination with an osmium photocatalyst, providing a higher penetration depth capable of polymerization. The development of this system allows for new ways to mold and 3D print polymers.
This technology has been validated in silicone molds, forming a free-standing gel upon polymerization.
IR CU22045, CU21095
Licensing Contact: Greg Maskel