Columbia Technology Ventures

Proton-conducting oxide membrane electrolysis cell

This technology is a high-capacity water electrolyzer for hydrogen production based on ultrathin proton-conducting oxide membranes with higher electrolysis efficiency than conventional polymer electrolyte membrane (PEM) electrolyzers.

Unmet Need: Clean, cost-efficient hydrogen that can rival fossil-derived hydrogen

Current efforts in creating electrolyzers include moving towards “zero-gap” polymer electrolyte membrane (PEM) electrolyzers with lower ionic resistances and comparable efficiencies to alkaline electrolyzers. However, the ultrathin Nafion membranes used in these “zero-gap” PEM electrolyzers typically still have a thickness of 125-250um. Attempts to reduce energy losses associated with ionic resistance from these thicknesses have limited success due to decreased manufacturing yields and mechanical failure. Additionally, achieving thicknesses below 50um will be difficult, and doing so may still not yield step changes in electrolyzer performance.

The Technology: Ultrathin oxide membrane for high capacity electrolyzer

This technology is a low-temperature water electrolyzer for hydrogen production that uses ultrathin oxide membranes to increase efficiency compared to conventional polymer electrolyte membrane (PEM) electrolyzers. This technology uses proton-conducting oxide membrane electrolyzers composed of oxidized silicon, titanium, or tungsten, with lower ionic resistance. This allows the technology to increase electrolysis efficacy by 20% at high current densities while being several orders of magnitude thinner than conventional Nafion electrolyzers. This technology also has a lower expected capital cost than today’s PEM electrolyzers, making it a competitive tool for the effective production of clean hydrogen that can compete with fossil-derived hydrogen.

Applications:

  • Clean energy production
  • Water electrolysis
  • Electrochemical CO2 conversion
  • Hydrogenation reactions
  • Electroorganic synthesis
  • Fuel cell
  • N2 reduction to NH3

Advantages:

  • Reduces membrane size by 2-4 orders of magnitude than conventional Nafion membranes
  • Reduces ionic resistances
  • Increases electrolysis efficiency by 20% at high current densities (> 4 A/cm2) compared to conventional PEM electrolyzers
  • Enables clean hydrogen production
  • Cost-effective

Lead Inventor:

Daniel Esposito, Ph.D.

Patent Information:

Patent Pending (WO/2024/197118)

Related Publications:

Tech Ventures Reference: